مقاله Preparation of nanocomposite membranes of propylsulfonated Poly[2,2′در(mدرpyrazolidene)در5,5′درbibenzimidazol
مقاله Preparation of nanocomposite membranes of propylsulfonated Poly[2,2′در(mدرpyrazolidene)در5,5′درbibenzimidazole] / surface modified nanopartices as Proton Exchange Membrane for Fuel Cell Application با word دارای 4 صفحه می باشد و دارای تنظیمات در microsoft word می باشد و آماده پرینت یا چاپ است
فایل ورد مقاله Preparation of nanocomposite membranes of propylsulfonated Poly[2,2′در(mدرpyrazolidene)در5,5′درbibenzimidazole] / surface modified nanopartices as Proton Exchange Membrane for Fuel Cell Application با word کاملا فرمت بندی و تنظیم شده در استاندارد دانشگاه و مراکز دولتی می باشد.
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توجه : در صورت مشاهده بهم ریختگی احتمالی در متون زیر ،دلیل ان کپی کردن این مطالب از داخل فایل ورد می باشد و در فایل اصلی مقاله Preparation of nanocomposite membranes of propylsulfonated Poly[2,2′در(mدرpyrazolidene)در5,5′درbibenzimidazole] / surface modified nanopartices as Proton Exchange Membrane for Fuel Cell Application با word،به هیچ وجه بهم ریختگی وجود ندارد
بخشی از متن مقاله Preparation of nanocomposite membranes of propylsulfonated Poly[2,2′در(mدرpyrazolidene)در5,5′درbibenzimidazole] / surface modified nanopartices as Proton Exchange Membrane for Fuel Cell Application با word :
سال انتشار: 1388
محل انتشار: سومین کنفرانس نانوساختارها
تعداد صفحات: 4
چکیده:
Propylsulfonated Poly 2,2′-(m-pyrazolidene)-5,5′-bibenzimidazole] (PSPPBI) was ynthesized from Poly[2,2′-(m-pyrazolidene)-5,5′-bibenzimidazole] (PPBI) and propansultone in DMSO using anionically reaction. PPBI was prepared from pyrazole-3,5-dicarboxylic acid and 3,3′,4,4′-tetraaminobiphenyle (TAB) through polycondensation reaction in polyphosphoric acid (PPA) with suitable viscosity. The modification of silica nanoparticles were confirmed by free radical polymerization of vinylimidazole and sulfonated vinylbenzene to surface bonded initiator. The proton
conductivity of nanocomposite membranes prepared with modified nanoparticles was higher than pure propylsulfonated polymer membrane. While, The nanocomposite membrane obtained from PSPPBI and unmodified silica nanoparticles was lower than pure PSPPBI and PPBI membtanes. The proton conductivity of membranes was measured by Electrochemical Impedance Spectroscopy (EIS) method. The structure of synthesized polymer was characterized by using FT-IR and 1H-NMR spectroscopy. Inherent viscosity was measured in order to determine the polymer molecular weight. Thermogravimmetery analysis (TGA) was carried out to investigate the thermal stability characteristics. The morphological study of modified nanoparticles was investigated with AFM method.
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